There are Di-Electric unions available that have a plastic separator to cut down or eliminate the galvanic action of the dissimilar metals. They don't cost that much, and you should only need two. I used them on my water/water heat exchangers.
My propane boiler has a low water cut off, it is in the output side of the boiler in the middle of a 3' vertical run. So in theory it should shut off the flame even while the boiler is full of water. I asked a plumber about it, and he said it is code. In my previous houses, the boiler did not have a cut-off. Just more parts to go bad and need replacement.
Greg L