My buddy Scott got me thinkin when he said dry air is heavier than wet air (I hope you don't mind I mentioned you Scott, you have my regard as being one of the 'smart' fellas around here). I'm not real fluent in the gas laws department but I like science and am slowly catching on lol.
Avogadro's law states that equal volumes of gases at the same temperature and pressure contain an equal number of molecules. Nitrogen and oxygen make up a bulk of our atmosphere. Water vapor is part of that also. What's interesting about water vapor is that a molecule of H2O has a molecular weight of 18.02. N2 (atmospheric nitrogen) is 28.0134 and O2 (atmospheric oxygen) is 31.9988. So, when calculating the weight of a cubic foot of humid air and comparing it to a cubic foot of dry air (temp and pressure the same), the humid air will actually be lighter.... It's lighter because the water vapor displaces some of the nitrogen and oxygen molecules (Avogadro's law). Who'd a thought? I know, right?
So, how does this affect our chimneys? The components of our coal exhaust are mainly nitrogen (78%), carbon dioxide and unused oxygen.. Turns out that the molecular weight of CO2 is 44.01 which is heavier than all of them. A minor component Sulfur Dioxide (Sulphur Dioxide) is 64.06. After looking at these molecular weights its amazing our chimneys draft at all lol. But, our chimneys work since the air in them is lighter than the outside air because of temperature difference.
So here's were my speculation comes in. If we introduce an atmosphere that is humid (and lighter) then the bar is raised, when it comes to making the gases in the chimney lighter than the outside air to create draft. If we introduce an atmosphere that is dry and heavier, then the bar is lowered when it comes to making the gases in the chimney lighter so that they can rise. My conclusion on this is that a humid atmosphere actually favors chimney drafting .
Thoughts and comments welcome.
I am a sick man with a coal stove...
Edit -
It's the other way around...My conclusion on this is that a humid atmosphere actually favors chimney drafting .